|
|
Volume 82, Issue 1
Received, 5th June, 2010, Accepted, 26th July, 2010, Published online, 27th July, 2010. |
| PDF (343KB) |
|
| Decarboxylative C-C Bond Cleavage Reactions via Oxapalladacycles |
Masanari Kimura,* Tomohiko Kohno, Kei Toyoda, and Takamichi Mori
Department of Applied Chemistry, Faculty of Engineering, Nagasaki University, 1-14, Bunkyo-machi, Nagasaki 852-8521, Japan |
|
Abstract
In the presence of Pd(0) catalyst and triethylborane, 3-hydroxy-4-pentenoic acids undergo C-C bond cleavage reactions via oxapalladacyclopentanones to provide conjugated dienes with evolution of carbon dioxide. |
|
Graphical Abstract
 |
|
| Corresponding author; email: masanari@nagasaki-u.ac.jp |
|
|
