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Volume 81, Issue 9 ( September, 1, 2010 ), Pages 2139-2142
Received, 23rd June, 2010, Accepted, 20th July, 2010, Published online, 21st July, 2010. |
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| One-Step Construction of 6-Aza-2-thiabicyclo[3.3.1]nona-3,7-diene Framework |
Nagatoshi Nishiwaki* and Kazuya Kobiro
School of Science and Technology, Kochi University of Technology, Tosayamada-cho, Kochi, 782-8502, Japan |
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Abstract
The 6-aza-2-thiabicyclo[3.3.1]nona-3,7-diene framework was constructed upon treatment of dielectrophilic 3,5-dinitro-1-methyl-2-pyridone with S,C-dinucleophilic ethyl 3-thioxobutanoate, in which two moieties are connected by forming two bonds in the single manipulation. |
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Graphical Abstract
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Keywords
1. Dinitropyridone
2. Bicyclic Compound
3. Thioketo Ester
4. Bridgehead Coupling
5. Stepwise Addition
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| Corresponding author; email: nishiwaki.nagatoshi@kochi-tech.ac.jp |
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