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Abstract

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Communication | Special issue | Vol 46, No. 1, 1997, pp.71-76
Published online:
DOI: 10.3987/COM-97-S25
Oxidation of Amines with Hypervalent tert-Butylperoxyiodanes: Synthesis of Imines and tert-Butylperoxyamino Acetals

Masahito Ochiai,* Daisuke Kajishima, and Takuya Sueda

*Faculty of Pharmaceutical Sciences, University of Tokushima, Sho-machi, Tokushima 770-8505, Japan

Abstract

Reaction of secondary amines with 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one (2) undergoes dehydrogenation to afford imines in the presence of K2CO3, while oxidation of tertiary amines without base produces tert-butylperoxyamino acetals.

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