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Review | Special issue | Vol 49, No. 1, 1998, pp.499-530
Published online:
DOI: 10.3987/REV-98-SR1
Pictet-Spengler Reactions of Nb-Hydroxytryptamines and Their Application to the Synthesis of Eudistomins

Tohru Hino and Masako Nakagawa*

*Faculty of Pharmaceutical Sciences, Chiba University, 1-33, Yayoi-cho, Inage-ku, Chiba-shi 263-8522, Japan

Abstract

Methods for preparing Nb-hydroxytryptamines, their Pictet-Spengler reactions with various aldehydes via nitrones, and their asymmetric inductions are reviewed. Syntheses of oxathiazepine-containing eudistomins and related natural products which incorporate these reactions are also reviewed.

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