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Paper | Special issue | Vol 66, No. 1, 2005, pp. 263 - 273
Published online: 11th October, 2005
DOI: 10.3987/COM-05-S(K)16
Planar-Chiral Ionic Liquids. Cyclophane-Type Imidazolium Salts with a C(2)-C(4) Bridge

Yasuhiro Ishida, Hiroyuki Miyauchi, and Kazuhiko Saigo*

*Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract

Novel chiral ionic liquids with planar chirality was synthesized, which were based on cyclophane-type imidazolium salts with a dodecamethylene bridge connecting the imidazolium C(2) and C(4) positions. Their potential utility as chiral solvents was demonstrated by 1H NMR spectroscopy and DSC measurement.

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