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Paper | Special issue | Vol 77, No. 1, 2009, pp. 351 - 364
Published online: 31st July, 2008
DOI: 10.3987/COM-08-S(F)26
A Transannular Diels-Alder Strategy to the Construction of the CDE Ring System of Nakiterpiosin

Hiroyoshi Takamura,* Yuji Yamagami, Tomonori Ito, Masahiro Ito, Hirokazu Arimoto, Isao Kadota, and Daisuke Uemura

*Division of Chemsitry and Biochemistry, Graduate School of Natural Science and Technology, Okayama University

Abstract

The transannular Diels-Alder (TADA) reaction was applied to the synthesis of the CDE ring system of nakiterpiosin (1). TADA product 28 is a key intermediate toward the total synthesis of 1.

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