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Paper | Special issue | Vol 77, No. 2, 2009, pp. 1079 - 1088
Published online: 2nd October, 2008
DOI: 10.3987/COM-08-S(F)87
Preparation of Azulene Substituted Pyrazine and Quinoxaline Derivatives

Nozomi Furuta, Takuo Mizutani, Akira Ohta, and Kunihide Fujimori*

*Department of Chemistry, Faculty of Science, Shinshu University, Asahi, Matsumoto 390-8621, Japan

Abstract

2,3-Di(2-azulenyl)pyrazines and -quinoxalines were obtained by the reaction of di(2-azulenyl)ethanedione with diamines. Cyclodehydrogenation reaction of the pyrazine and quinoxaline derivatives with manganese dioxide afforded the corresponding azulene-fused quinoxaline and phenazine derivatives, respectively.

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