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Abstract

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Paper | Special issue | Vol 82, No. 2, 2011, pp. 1477 - 1488
Published online: 14th September, 2010
DOI: 10.3987/COM-10-S(E)99
Step-Growth Control in Template-Directed Polymerization

Xiaoyu Li, Andres F. Hernandez, Martha A. Grover, Nicholas V. Hud, and David G. Lynn*

*Department of Chemistry and Biology, Emory University, Emerson Hall, Atlanta, GA 30322, U.S.A.

Abstract

A self-organizing process is described that combines DNA template association thermodynamics and kinetic reductive amination to translate polymer sequence information into amine nucleoside polymers. The developed kinetic model analyses allowed this process to be extended to the translation of templates as long as catalytic ribozymes.

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