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Abstract

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Short Paper | Special issue | Vol 88, No. 2, 2014, pp. 1519 - 1526
Published online: 21st August, 2013
DOI: 10.3987/COM-13-S(S)54
Iodoetherification of Conformationally Restricted Dienyl Alcohols: Unexpected Formation of Oxocenes by 8-endo-mode Oxacyclizations

Kristen L. Stoltz, Andrea-Nekane R. Alba, Frank E. McDonald,* Marika B. Wieliczko, and John Bacsa

*Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, GA 30322, U.S.A.

Abstract

Iodine-promoted oxacyclizations of a family of conformationally restricted dienyl alcohols consistently afford oxocenes, arising from 8-endo-mode cyclizations.

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