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Abstract

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Paper | Special issue | Vol 101, No. 2, 2020, pp. 453 - 460
Published online: 14th August, 2019
DOI: 10.3987/COM-19-S(F)25
Photo-Irradiation-Promoted Aminoetherification of Glycals with N-Acyliminoiodinane and Alcohols

Sota Masakado, Yusuke Kobayashi, and Yoshiji Takemoto*

*Graduate School of Pharmaceutical Sciences, Kyoto University, 46-29 Yoshida-shimoadachi-machi, Sakyo-ku, Kyoto 606-8501, Japan

Abstract

An efficient trifluoroacetamido-etherification of glycals was achieved using N-acyliminoiodinane and various alcohols under photo-irradiation. This reaction was successfully applied to the efficient synthesis of biologically active compounds.

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