Online article for Non-subscribers

Pay per view

Heterocycles has a pay-per-view service for Non-subscribers.
You will be able to directly purchase the full text article through PayPal.
Your purchased Paper can be downloaded after the payment is completed.
An e-mail will be sent the URL to download the paper.
If you have any questions, please contact: purchase@heterocycles.com

Price: ¥ 4,320 (Yen only)
Period: This Article can be accessed for 7 days.

Note | Regular issue | Vol 55, No. 6, 2001, pp.1189-1194
Published online, 1st January, 1970
DOI: 10.3987/COM-01-9224
Reaction of 2-Chloro-1-azaazulene with Diphenylcyclopropenone; Dimerization of the Cycloadduct Attended by cine-Substitution and Rearrangement

Noritaka Abe,* Hiroyuki Fujii, and Akikazu Kakehi

*Department of Chemistry, Faculty of Science, Yamaguchi University, 1677-1 Yoshida, Yamaguchi 753-8512, Japan

Abstract

2-Chloro-1-azaazulene reacted with diphenylcyclopropenone to give 3,4-diphenyl-2a,5-dihydro-2H-2a-azabenz[cd]azulene-2,5-dione and 6-[(3,4-diphenyl-5-oxo-2a,5-dihydro-2H-2a-azabenz[cd]azulen-2-ylidene)-methyl]-3,4-diphenyl-2a,5-dihydro-2a-azaacenaphtylen-5-one; the latter would be produced via cycloaddition and a successive cine-substitution followed by rearrangement.