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Communication | Regular issue | Vol 60, No. 1, 2003, pp.15-22
Published online, 25th November, 2002
DOI: 10.3987/COM-02-9639
■ Electrolytic Partial Fluorination of Organic Compounds. 66. Anodic Fluorination of (Thiazol-2-yl)acetonitriles

Sayed M. Riyadh and Toshio Fuchigami*

*Department of Electronic Chemistry, Tokyo Institute of Technology, 4259 Nagatsuta-cho, Midori-ku, Yokohama 226-8501, Japan

Abstract

Electrochemical partial fluorination of (4-arylthiazol-2-yl)acetonitriles was carried out to afford the corresponding (4-aryl-5-fluoro-5H-thiazol-2-ylidene)acetonitriles as main products in addition to (4-aryl-5-fluorothiazol-2-yl)acetonitriles and (4-arylthiazol-2-yl)fluoroacetonitriles. AM1 calculations were conducted to compare the stability of the fluorinated products.