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Paper | Regular issue | Vol 65, No. 10, 2005, pp.2357-2367
Published online, 9th August, 2005
DOI: 10.3987/COM-05-10480
■ Five Monoterpene Glycosides from Zingiberis Rhizome (Shokyo)

Yumiko Hori, Tsuyoshi Miura, Yukiye Wakabayashi, Motonori Fukumura, Yasuaki Hirai, Kazuo Toriizuka, Yoshiyuki Kuchino, and Yoshiteru Ida*

*School of Pharmaceutical Sciences, Showa University, 1-5-8 Hatanodai, Shinagawa-ku, Tokyo 142-8555, Japan

Abstract

Five monoterpene glycosides were isolated from Zingiberis rhizome (Japanese name: Shokyo). They were characterized to be (+)-angelicoidenol 2-O-β-D-glucopyranoside (1), (+)-angelicoidenol 2-O-β-D-glucopyranosido-5-O-β-D-glucopyranoside (2), (+)-angelicoidenol 2-O-β-D-apiofuranosyl(1→6)-β-D-glucopyranoside (3), (+)-angelicoidenol 2-O-[6’-O-S-3-hydroxy-3-methylglutaryl]-β-D-glucopyranoside (4) and its methyl ester (5), respectively, by means of spectroscopic and chemical methods. Of them, the new glycosides (2, 3 and 4) were named zingiberosides A, B and C, respectively.