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Communication | Regular issue | Vol 68, No. 1, 2006, pp.1-4
Published online, 28th October, 2005
DOI: 10.3987/COM-05-10570
Palladium-catalyzed Cross-Coupling Reaction of 4-Methylthiazole and 2-Trimethylsilylthiazoles with Biaryl Triflates

Osamu Hara, Taiju Nakamura, Fumihiko Sato, Kazuishi Makino, and Yasumasa Hamada*

*Faculty of Pharmaceutical Sciences, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

Abstract

2-Trimethylsilylthiazoles serve as an efficient counterpart for direct palladium-catalyzed cross-coupling reaction with aromatic triflates without any fluoride anion source to afford 2-arylthiazoles.