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Communication | Special issue | Vol 66, No. 1, 2005, pp.45-50
Published online, 2nd September, 2005
DOI: 10.3987/COM-05-S(K)12
Studies on the Preparation of 1,5-Methanoazocinoindole Based on Indolylborate

Minoru Ishikura,* Norinobu Takahashi, Hidekazu Takahashi, and Kazuo Yanada

*Faculty of Pharmaceutical Sciences, Health Sciences University of Hokkaido, Ishikari-Tobetsu, Hokkaido 061-0293, Japan

Abstract

Conversion of piperidine (8), readily available from the palladium catalyzed tandem cyclization-cross-coupling reaction of indolylborate (6) with bromide (7), to 1H-1,5-methanoazocino[4,3-b]indole (15) through piperidine (14) was investigated.