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Communication | Special issue | Vol 66, No. 1, 2005, pp.91-94
Published online, 14th October, 2005
DOI: 10.3987/COM-05-S(K)35
The Synthesis of Heteroarylazulene

Taku Shoji, Shigeru Kikuchi, Shunji Ito, and Noboru Morita*

*Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan


Palladium-catalyzed cross-coupling reaction of 2- and 6-haloazulenes with lithium tri(heteroaryl)magnesates gave corresponding heteroarylazulenes in excellent yields which were independent of binding position.