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Obituary
Zenichi Yoshida (1925-2023)
Zenichi Yoshida (1925-2023)
Professor. Zenichi Yoshida,
a member of the Honorary Advisors of HETEROCYCLES (1975-1998),
has passed away on May 4, 2023 at the age of 97.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
May 11, 2023
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Communication | Special issue | Vol 66, No. 1, 2005, pp.101-106
Published online, 14th October, 2005■ New Utilizations of Optically Active Homoallylamines: Highly Stereoselective Synthesis of Cyclic Guanidine and Thiourea
Published online, 14th October, 2005
DOI: 10.3987/COM-05-S(K)43
■ New Utilizations of Optically Active Homoallylamines: Highly Stereoselective Synthesis of Cyclic Guanidine and Thiourea
Reiko Yanada, Akira Kaieda, Kazuo Yanada, and Yoshiji Takemoto*
*Graduate School of Pharmaceutical Sciences, Kyoto University, 46-29 Yoshida-shimoadachi-machi, Sakyo-ku, Kyoto 606-8501, Japan
Abstract
Halocyclizations of optically active homoallylguanidine and homoallylthiourea were examined. These reactions proceeded stereoselectively to give six membered cyclic guanidines and thiourea. High 1,3-asymmetric induction by the homoallylic substituents is observed in these halocyclizations.
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