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Communication | Special issue | Vol 67, No. 2, 2006, pp.503-506
Published online, 16th September, 2005
DOI: 10.3987/COM-05-S(T)43
Tin(II) Iodide-catalyzed Selective Aziridination or 1,2-Diamination of Alkenes with Chloramine-T

Yoshiro Masuyama,* Masaru Ohtsuka, Masaru Harima, and Yasuhiko Kurusu

*Department of Chemistry, Faculty of Science and Technology, Sophia University, Kioi-cho 7-1, Chiyoda-ku, Tokyo 102-8554, Japan

Abstract

Tin(II) iodide selectively catalyzes reactions of alkenes in acetonitrile to afford the corresponding aziridines by the use of one equimolar amount of Chloramine-T [Ts(Cl)N-] at room temperature and to afford the corresponding 1,2-diamines by the use of excess Chloramine-T at 50 °C.