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Communication | Special issue | Vol 72, No. 1, 2007, pp.157-161
Published online, 23rd February, 2007
DOI: 10.3987/COM-06-S(K)36
The Regiochemistry of the o-Claisen Rearrangement of Bis-(alloxy)polycyclic Aromatics

George Majetich,* Jianhua Yu, Yang Li, and Scott H. Allen

*Department of Chemsitry, The University of Georgia, Athens, Georgia 30602, U.S.A.

Abstract

The o-Claisen rearrangement of bis-(allyloxy) naphthalenes, anthracenes and phenanthrenes is regiospecific and is consistent with resonance theory and molecular orbital calculations.