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Obituary
Zenichi Yoshida (1925-2023)
Zenichi Yoshida (1925-2023)
Professor. Zenichi Yoshida,
a member of the Honorary Advisors of HETEROCYCLES (1975-1998),
has passed away on May 4, 2023 at the age of 97.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
May 11, 2023
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Paper | Regular issue | Vol 71, No. 8, 2007, pp.1787-1800
Published online, 25th May, 2007■ Stereoselective Synthesis of D-1-Deoxynojirimycin and Its Stereoisomers
Published online, 25th May, 2007
DOI: 10.3987/COM-07-11066
■ Stereoselective Synthesis of D-1-Deoxynojirimycin and Its Stereoisomers
In Su Kim, Ho Young Lee, and Young Hoon Jung*
*College of Pharmacy, Sung Kyun Kwan University, 300 Jangangu, Chonchondong, Suwon 440-746, Korea
Abstract
A stereoselective synthesis of D-1-deoxynojirimycin (1), D-1-deoxymannojirimycin (2), and D-1-deoxyallonojirimycin (3) was achieved via the regioselective and diastereoselective amination of anti-1,2-dibenzyl ether using chlorosulfonyl isocyanate (CSI), ring-closing metathesis, diastereoselective dihydroxylation, and the regioselective stereochemical inversion of the resulting diol.
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