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Paper | Regular issue | Vol 75, No. 4, 2008, pp.839-846
Published online, 11th January, 2008
DOI: 10.3987/COM-07-11258
The Reaction of Hexachlorocyclotriphosphazatriene with Bromoneopentyl Glycol

Hanife Ibisoglu,* Ferda Hacivelioglu, and Adem Kiliç

*Department of Chemistry, Gebze Institute of Technology, Gebze 41400, Kocaeli, Turkey

Abstract

In the present work, novel phosphazene derivatives, monospiro- (1), dispiro- (2), and trispiro-2,2-bis(bromomethyl)-1,3-propandioxy (3) substituted cyclotriphosphazatrienes were synthesized with the reaction of bromoneopentyl glycol(2,2-bis(bromomethyl)-1,3-propandiol) with hexachlorocyclotriphosphazatriene, N3P3Cl6. The structures of the compounds were determined by elemental analysis, mass spectrometry, 1H and 31P NMR spectroscopy. The thermal properties of the compounds (1), (2) and (3) were investigated by DSC and TGA.