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Communication | Special issue | Vol 74, No. 1, 2007, pp.259-263
Published online, 2nd November, 2007
DOI: 10.3987/COM-07-S(W)81
Stereoselective Synthesis of the GHI-Ring of Maitotoxin, a Marine Polycyclic Ether

Masanori Satoh, Masaki Mori, and Tadashi Nakata*

*Department of Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka 1-3, Shinjuku-ku, Tokyo 162-8601, Japan

Abstract

The GHI-ring of maitotoxin, a marine polycyclic ether, was stereoselectively synthesized by way of SmI2-induced reductive cyclization of β-alkoxyacrylate and aldehyde.