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Paper | Special issue | Vol 74, No. 1, 2007, pp.895-912
Published online, 4th December, 2007
DOI: 10.3987/COM-07-S(W)84
Transition Metals in Organic Synthesis, Part 84. Application of Iron- and Nickel-Mediated Coupling Reactions to the Total Synthesis of the Neuronal Cell Protecting Substance (±)-Carquinostatin A

Wolfgang Fröhner, Kethiri R Reddy, and Hans-Joachim Knölker*

*Institute of Organic Chemistry, Technical University Dresden, Bergstrasse 66, D-01069 Dresden, Germany


Using iron- and nickel-mediated coupling reactions as key steps a convergent and highly efficient total synthesis of the potent neuronal cell protecting alkaloid (±)-carquinostatin A has been accomplished.