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Paper | Special issue | Vol 76, No. 2, 2008, pp.1087-1102
Published online, 15th May, 2008
DOI: 10.3987/COM-08-S(N)27
Investigations on the Reactions of Thioamides and Related 1,3-Diazabuta-1,3-dienes with Dimethyl Acetylenedicarboxylate: Synthesis of Novel Functionalized Heterocycles

Alka Marwaha, Vishal Sudan, and Mohinder P. Mahajan*

*Department of Applied Chemistry, Guru Nanak Dev University, Amritsar - 143005, Punjab, India


The manuscript describes an investigation on the reaction pathways followed in the reactions of variedly substituted thioamides and the corresponding 1,3-diazabuta-1,3-dienes with dimethyl acetylene dicarboxylate. The mechanistic rationales for the reactions pathways followed have been plausibly explicated. The study assumes considerable significance because of the formation of novel functionalized heterocycles.