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Paper | Special issue | Vol 76, No. 2, 2008, pp.1103-1119
Published online, 15th May, 2008
DOI: 10.3987/COM-08-S(N)64
Synthesis of Thiochromans Based on Indirect Cation Pool Method

Kouichi Matsumoto, Koji Ueoka, Shunsuke Fujie, Seiji Suga,* and Jun-ichi Yoshida*

*Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan


A method for the synthesis of thiochromans based on the reactions of stilbenes and alkoxycarbenium ion pools, which were generated and accumulated by the reaction of anodically generated ArS(ArSSAr)+ with thioacetals, has been developed.