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Communication | Special issue | Vol 76, No. 2, 2008, pp.1023-1026
Published online, 19th May, 2008
DOI: 10.3987/COM-08-S(N)75
Preparation and Electrochemical Property of Octabutylphthalocyanine Fused with Four TTF Units

Takeshi Kimura,* Dai Watanabe, and Toshiharu Namauo

*Center for Instrumental Analysis, Iwate University, Morioka, Iwate 020-8551, Japan

Abstract

3,6-Dibutylphthalonitrile (3) fused with a TTF unit was prepared and treated with lithium in n-pentanol to produce octabutyltetrakis(tetrathiafulvaleno)phthalocyanine (5). The structure of the product was determined by 1H NMR and FAB MS. Electrochemical and optical properties of compound (5) were estimated by cyclic voltammetry and UV-vis spectroscopy.