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Paper | Regular issue | Vol 27, No. 10, 1988, pp.2423-2429
Published online, 1st January, 1970
DOI: 10.3987/COM-88-4659
Structure and Synthesis of Cucumopine, a New Crown Gall and Hairy-root Opine

Elisabeth Davioud, Jean-Charles Quirion, Max E. Tate, Jacques Tempé, and Henri-Philippe Husson*

*Institut des Chimie des Substances Naturelles, C.N.R.S., 1 avenue de la Terrasse, Bat. 27, 91198 Gif-sur-Yvette Cedex, France

Abstract

The opine known as cucumopine 1 produced by crown gall tumours and hairyroot exhibited chemical and spectroscopic data corresponding to 4-(2-carboxyethy1)-4,5,6,7-tetrahydroimidazo[4,5-c]pyridine-4,6-dicarboxylic acid. The identification was verified by a biogenetic type synthesis from L-histidine and α-ketoglutaric acid.