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Paper | Special issue | Vol 30, No. 2, 1990, pp.939-947
Published online, 1st January, 1970
DOI: 10.3987/COM-89-S89
Photoinduced Generation of Glycosyl Cations from Thioglycosides

Gary W. Griffin, Nayanie C. Bandara, Margaret A. Clarke, Wing-Sum Tsang, Per J. Garegg,* S. Oscarson, and B. Azmy Silwanis

*Department of Organic Chemistry, Arrhenius Laboratory, University of Stockholm, SE-10691 Stockholm, Sweden

Abstract

Photochemically induced clevage of thioaryl β-D-glucopyranosides using 1,4-dicyanonaphthalene as an electron-transfer agent, produces glycosyl cations potentially useful in glycosylation reactions.