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Communication | Special issue | Vol 30, No. 2, 1990, pp.775-778
Published online, 1st January, 1970
DOI: 10.3987/COM-89-S98
A Mild and Rapid 1,2-trans-Glycosidation Method via Benzoyl-protected Glycopyranosyl P,P-Diphenyl-N-(p-toluenesulfonyl)phosphinimidates

Shun-ichi Hashimoto, Takeshi Honda, and Shiro Ikegami*

*Faculty of Pharmaceutical Sciences, Teikyo University, 1091-1, Sagamiko, Kanagawa 199-0195, Japan

Abstract

A highly efficient 1,2-trans-glycosidation reaction with a range of acid-labile alcohols has been developed by employing benzoyl-protected glycopyranosyl P,P-diphenyl-N-(p-toluenesulfonyl)phosphinimidates as glycosyl donors.