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Paper | Regular issue | Vol 34, No. 2, 1992, pp.341-347
Published online, 1st January, 1970
DOI: 10.3987/COM-91-5926
Synthesis and Attempted [4+2] Cycloaddition Reaction of 2,4,6-Tris(phenylseleno and aryltelluro)-1,3,5-triazines with Diethyl Acetylenedicarboxylate

Hiroyuki Tani,* Tokuo Inamasu, and Hitomi Suzuki*

*Advanced Instrumentation Center for Chemical Analysis, Ehime University, Bunkyo-cho 2-5, Matsuyama 790, Japan

Abstract

2,4,6-Tris(phenylseleno and aryltelluro)-1,3,5-triazines were synthesized by the reaction of 2,4,6-trichloro-1,3,5-triazine with corresponding arylchalcogenide anions. These 2,4,6-tris(arylchalcogeno)-1,3,5-triazines failed to undergo the Diels-Alder reaction with diethyl acetylenedicarboxylate.