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■ Mechanistic Inversion of Photoinitiated Electron Transfer Processes in Aryl Imidazolidinones

Paul H. Mazzocchi,* Nai Yong Jing, and Kazuaki Oda

*Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, U.S.A.

Abstract

Aryl imidazolidinones having o-carboxylic acid and ester containing aryl substituents were found to undergo different photochemical reactions. Although both reactions are suggested to proceed by electron transfer mechanisms, the donor and acceptor groups are interchanged.