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Paper | Regular issue | Vol 34, No. 4, 1992, pp.739-745
Published online, 1st January, 1970
DOI: 10.3987/COM-91-5954
Synthesis of New Carbocyclic Analogues of Oxetanocin A and Oxetanocin G

Pascal Pecquet, François Huet,* Michel Legraverend,* and Emile Bisagni

*URA CNRS 1387, Institut Curie-Biologie, Batiment 110-112, Centre Universitaire, 91405 Orsay Cedex, France

Abstract

The synthesis of cis-3-amino-1-cyclobutanemethanol has been performed in six steps (59.6% yield) from cis-1,3-cyclobutanedicarboxylic anhydride. This allowed us to obtain two new carbocyclic analogues of oxetanocin A and oxetanocin G related to 7-deazaadenosine and 7-deazaguanosine