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Paper | Regular issue | Vol 34, No. 7, 1992, pp.1317-1324
Published online, 1st January, 1970
DOI: 10.3987/COM-92-5998
Thienocyclopenta[2,3-b]aziridin-5-one: Cleavage in Acidic Medium

Patrick Dallemagne, Juan Carlos Pilo, Sylvain Rault, Max Robba,* Michel Saux, and Alain Carpy

*Laboratoire de Chimie Thérapeutique, U. F. R. des Sciences Pharmaceutiques, 1 rue Vaubénard, 14032 CAEN cedex, France

Abstract

Cleavage of thienocyclopenta[2,3-b]aziridin-5-one leads to cis and trans isomers of hydroxyoxocyclopenta[b]thienylammonium chlorides whose structures are established by X-ray analysis and unequivocal synthesis. The mechanism of cleavage is studied.