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Communication | Regular issue | Vol 34, No. 8, 1992, pp.1503-1506
Published online, 1st January, 1970
DOI: 10.3987/COM-92-6064
Reaction of Quadricyclane with Electron Deficient p-Benzoquinones

Ken-ichi Hirao,* Tohru Yokozawa, Asami Yamashita, and Tomoki Watanabe

*Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060, Japan

Abstract

Quadicyclane reacted thermally in a [π2+σ2+σ2] manner with 2,3-dichloro-5,6-dicyano-p-benzoquinone (DDQ) and chloranil to give cyclobutanes and a spiro oxetane, respectively.