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Communication | Regular issue | Vol 34, No. 12, 1992, pp.2247-2252
Published online, 1st January, 1970
DOI: 10.3987/COM-92-6147
Branched Chain Carbohydrate Lactones from a Tandem SmI2 Deoxygenation-Carbonyl Addition Reaction

Eric J. Enholm* and Shujun Jiang

*Department of Chemistry, University of Florida, Gainesville, Florida 32611, U.S.A.

Abstract

Treatment of a carbohydrate lactone with a ketone in the presence of SmI2-HMPA produces a deoxygenation/carbonyl addition reaction to afford new C2-branched chain carbohydrates.