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Paper | Regular issue | Vol 36, No. 6, 1993, pp.1253-1262
Published online, 1st January, 1970
DOI: 10.3987/COM-92-6273
N-Sulfonylbenzotriazoles. Part 2. Reactions of 1,1’-Sulfonyldibenzotriazole and 1-Benzenesulfonyl-1,2,4-triazole with Alcohols; a New Approach to N-Alkylbenzotriazoles and N-Alkyl-1,2,4-triazoles

Alan R. Katritzky,* Gui-Fen Zhang, Juliuzs Pernak, and Wei-Qiang Fan

*Department of Chemistry, University of Florida, P. O. Box 117200, Gainesville, FL 32611-2046, U.S.A.

Abstract

1,1’-Sulfonyldibenzotriazole (3) reacts with sodium alkoxides to give N-alkylbenzotriazoles. With alkanols, benzotriazolium alkyl sulfates are produced. 1-Benzenesulfonyl-1,2,4-triazole with the sodium salts of alcohols gives 1-alkyl-1,2,4-triazoles. The mechanisms of these reactions are discussed.