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Paper | Regular issue | Vol 38, No. 5, 1994, pp.1103-1118
Published online, 1st January, 1970
DOI: 10.3987/COM-94-6684
Radical Reaction of 1-(2-Bromoarylmethyl)-2-silatetralins: Formation of Polycyclic Organosilicon Compounds

Akihisa Hirokawa, Atsuhiro Tatsuno, and Osamu Hoshino*

*Faculty of Pharmaceutical Sciences, Science University of Tokyo, 2641 Yamazaki, Noda, Chiba 278-8510, Japan

Abstract

Radical reaction of 1-(2-bromoarylmethyl)-2-silatetralins (4a-f) with Bu3SnH in boiling benzene containing AlBN was found to give novel tetracyclic (5a-f) and tricyclic (6a-f) organosilicon compounds, and 9-silylphenanthrenes (7a-c), respectively.