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Communication | Regular issue | Vol 41, No. 2, 1995, pp.249-253
Published online, 1st January, 1970
DOI: 10.3987/COM-94-6969
Synthesis and 1H Nmr Complexation Study of a Novel Macrocyclic Polyether Containing 1,1'-Biazulene Unit

Der-Seang Lee, Paw-Wang Yang, Tadayoshi Morita*, and Tetsuo Nozoe

*Department of Chemistry, Tohoku University, Aoba-ku, Sendai 980-77, Japan

Abstract

A new class of chiral macrocyclic polyethers containing 1,1’-biazulene unit was prepared from the reaction of 2,2’-dihydroxy-3,3’-bis(methoxycarbonyl)-1,1’-biazulene with tetra- or pentaethyleneglycol ditosylate by a high dilution technique. Complexation study with alkali metals by 1H nmr indicated ion selectivity for these macrocycles. The crystal structure was studied by X-ray diffraction.