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Paper | Special issue | Vol 40, No. 1, 1995, pp.231-240
Published online, 1st January, 1970
DOI: 10.3987/COM-94-S14
Imidoylbenzotriazoles: Stable Alternatives to Imidoyl Chlorides

Alan R. Katritzky*, Christian V. Stevens, Gui-Fen Zhang, Jinlong Jiang, and Norbert De' Kimpe

*University of Florida, Department of Chemistry, Center for Heterocyclic Compounds, P. O. Box 117200, Gainesville, FL 32611-7200, U.S.A.


Imidoylbenzotriazoles were prepared from the corresponding amides and 1,1’-sulfinyldibenzotriazole, generated in situ from 1-trimethylsilylbenzotriazole and thionyl chloride. The imidoylbenzotriazoles are stable precursors for the synthesis of imidates and thioimidates.