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■ One Pot exo-endo Isomerization in Bicyclic Adducts Arising from 1,3-Dipolar Cycloaddition Reactions of 7-oxanorbornene Derivatives

Odón Arjona, Araceli Mallo, and Joaqín Plumet

*Department of Organic Chemistry, Faculty of Chemistry, Complutense University, 28040 Madrid, Spain

Abstract

A new, one pot methodology to carry out the exo-endo isomerization of some tricyclic adducts derived from the cycloaddition of 7-oxabicyclo[2.2.1]hept-5-ene derivatives and nitrile oxides is described.