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Paper | Regular issue | Vol 41, No. 10, 1995, pp.2307-2312
Published online, 1st January, 1970
DOI: 10.3987/COM-95-7186
Formations of Organic Semiconductors: Bistropylium Ions Linked by Heterocyclic Moieties as Components of Charge Transfer Complex

Kazuaki Ito and Katsuhiro Saito*

*Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466, Japan

Abstract

Bistropylium ions linked by heterocyclic moieties were synthesized to measure their reduction potentials of -0.47 ~ -0.42 V vs. SCE. Charge transfer complexes between these bistropylium ions and radical anion of TCNQ showed conductivities of 7.7 X 10-4 ~ 7.7 X 10-5 Scm-1, indicating that they can be classified as semiconductors.