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Communication | Special issue | Vol 42, No. 2, 1996, pp.475-478
Published online, 1st January, 1970
DOI: 10.3987/COM-95-S58
Asymmetric Dialkylation of Chiral 2-Benzazepine Formamidines

A. I. Meyers and Richard Hutchings

*Department of Chemistry, Colorado State University, Fort Collins, CO 80523-1872, U.S.A.

Abstract

Repeated metallation and alkylation of an (S)-(+)-tertleucinol derived 2,3,4,5-tetrahydro-1H-2-benzazepine formamidine leads to the corresponding 1,1 -dialkyl-2-benzaepines in good yields and with excellent enantioselectivities.