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Communication | Special issue | Vol 47, No. 2, 1998, pp.679-683
Published online, 1st January, 1970
DOI: 10.3987/COM-97-S(N)105
anti-Selective Epoxidation of Primary 5-(tert-Butyldimethylsilyl)oxyallylic Alcohols with m-Chloroperoxybenzoic Acid

Kåre B. Jørgensen, Hiroyuki Koshino, and Tadashi Nakata*

*The Institute of Physical and Chemical Research, Wako-shi, Saitama 351-0198, Japan

Abstract

Epoxidation of primary 5-(tert-butyldimethylsilyl)oxyallylic alcohols with m-chloroperoxybenzoic acid produced anti-epoxides with high stereoselectivity.