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Note | Special issue | Vol 47, No. 2, 1998, pp.977-984
Published online, 1st January, 1970
DOI: 10.3987/COM-97-S(N)23
Ring Opening SN2’ Reactions of 1,4,5,8-Diepoxy-1,4,5,8-tetrahydroanthracenes by Organolithium Reagents

Odón Arjona,* Marisa León, and Joaquín Plumet*

*Departamento de Química OrgÁnica I., Facultad de Química., Universidad Complutense de Madridas, Ciudad Universitaria, E-28040 Madrid, Spain

Abstract

The nucleophilic SN2’ bridge opening of diepoxytetrahydroanthracenes with organolithium reagents to produce hydroanthracene derivatives shows a dependence of the excess of reagent as well as the relative stereochemistry of the oxygen bridge.