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Note | Regular issue | Vol 51, No. 1, 1999, pp.145-155
Published online, 1st January, 1970
DOI: 10.3987/COM-98-8333
CMR Spectra of N-Oxygenated Pyrazoles. I. 3,5-Dialkyl- and 3-Alkyl-5-phenyl-4-oxo-4H-pyrazole 1,2-Dioxides

Wayne E. Zeller,* Lynn S. Zeller, and John F. Hansen*

*Department of Chemistry, 305 Felmeley Hall, Campus Box 4160, Illinois State University, Normal, Illinois 61790-4160, U.S.A.

Abstract

The 13C NMR spectra of a series of 3,5-dialkyl- and 3-alkyl-5-phenyl-4-oxo-4H-pyrazole 1,2-dioxides were determined. Signals for the carbonyl carbon, C4 of the pyrazole, appeared at δ 186.2 to 188.1 ppm, while the C3 and C5 signals were found in the region of 105.8 to 112.8 ppm. The effect of structural variation of the alkyl groups on the chemical shift of C3 in a selected series of these compounds was investigated using published electronic and steric parameters. Strong correlations were observed with electronic parameter sets σ* and Eσ when augmented with a variety of published steric parameter sets.