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Zenichi Yoshida (1925-2023)
Zenichi Yoshida (1925-2023)
Professor. Zenichi Yoshida,
a member of the Honorary Advisors of HETEROCYCLES (1975-1998),
has passed away on May 4, 2023 at the age of 97.
I deeply express my regret over his death.
Kunio Ogasawara
Editor
May 11, 2023
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Communication | Special issue | Vol 50, No. 2, 1999, pp.645-652
Published online, 1st January, 1970■ An Efficient Synthesis of 5-Phosphorylated 1,3,2-Diazaphosphinines from β-Functionalized Enamines Derived from Phosphine Oxides and Phosphonates
Published online, 1st January, 1970
DOI: 10.3987/COM-98-S(H)83
■ An Efficient Synthesis of 5-Phosphorylated 1,3,2-Diazaphosphinines from β-Functionalized Enamines Derived from Phosphine Oxides and Phosphonates
Francisco Palacios,* Domitila Aparicio, Jesús M. de los Santos, and Jesús García
*Departamento de Química OrgÁnica, Facultad de Farmacia, Universidad del País Vasco, Apartado 450, 01080 Vitoria-Gasteiz, Spain
Abstract
An easy and efficient synthesis of 1,3,2-PIII-diazaphosphininones (3,4) substituted with a phosphine oxide or a phosphonate group in the 5-position is described. The key step is a cyclocondensation reaction of substituted β-enamino amides (1) to phosphorus trichloride and phenylphosphonous dichloride. Subsequent treatment of 1,3,2-PIII-diazaphosphininones (3) with elemental sulfur, water or hydrogen peroxide afforded the substituted 2-thio-(7,8) and 2-oxo-1,3,2-PV-diazaphosphininones (5,6,9).
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