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Paper | Regular issue | Vol 53, No. 4, 2000, pp.805-820
Published online, 1st January, 1970
DOI: 10.3987/COM-99-8819
A Synthesis and Transformations of Alkyl 2-[2-Cyano-2-(2-pyridinyl)ethenyl]amino-3-dimethylaminopropenoates. A One-Pot Synthesis of Pyrrolo[3,2-d ]pyrimidin-4-ones

Lucija Jukic, Jurij Svete, Amalija Golobic, Ljubo Golic, and Branko Stanovnik*

*Faculty of Chemistry and Chemical Technology, University of Ljubljana, Askerceva 5, P.O. Box 537, 1000 Ljubljana, Slovenia


Alkyl 2-[2-cyano-2-(2-pyridinyl)ethenyl]amino-3-dimethylaminopro-penoates (8) and (9) were transformed by heating into alkyl 2-[2-cyano-2- (2-pyridinyl)ethenyl]amino-3-[2-methoxycabonyl-4-(2-pyridinyl)-1H-pyrrol-3-yl]aminopropenoates (12) and (13). Compounds (8) and (9) can be transformed in the presence of primary aliphatic amines into substituted pyrrolo[3,2-d]pyrimidines (17-19).