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Paper | Special issue | Vol 52, No. 1, 2000, pp.253-260
Published online, 1st January, 1970
DOI: 10.3987/COM-99-S18
Direct Arylation of 2-Pyridones; Photostimulated SRN1 Reaction between Cesium Phenoxides and Chloro-2-pyridones

Hiroyuki Higuchi, Masayo Hattori, and Shigeru Ohmiya*

*Institute of Medicinal Chemistry, Hoshi University, 2-4-41 Ebara, Shinagawa-ku, Tokyo 142-8501, Japan


4-Hydroxyphenyl- (3 and 4) and 6-hydroxyphenyl-1-methyl-2-pyridones (6 and 7) were obtained by the photostimulated reaction of 4-chloro- (1) and 6-chloro-1-methyl-2-pyridone (5), respectively, with variously substituted cesium phenoxides (2). The reactions were proposed to proceed via an SRN1 mechanism.