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Communication | Special issue | Vol 52, No. 1, 2000, pp.99-102
Published online, 1st January, 1970
DOI: 10.3987/COM-99-S31
Studies Relating to the Synthesis of Laurenenynes: Construction of the Alkylidene Side Chain via [2,3]-Wittig-Still Rearrangement at the Anomeric Center of a Furanoside Derivative

Hideyuki Sugimura,* Yoshiki Hasegawa, and Kenji Osumi

*The Noguchi Institute, 1-8-1, Kaga, Itabashi-ku, Tokyo 173-0003, Japan

Abstract

The construction of the C6 alkylidene side chain of laurenenynes has been investigated using the [2,3]-Wittig-Stil1 rearrangement at the anomeric position of an appropriate glycofuranoside derivative, followed by further chemical transformations.