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Communication | Regular issue | Vol 4, No. 5, 1976, pp.985-988
Published online, 1st January, 1970
DOI: 10.3987/R-1976-05-0985
The Partial Synthesis of 16-epi-Pleiocarpamine

Shin-ichiro Sakai* and Nobuo Shinma

*Faculty of Pharmaceutical Sciences, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan

Abstract

An indole alkaloid, 16-epi-pleiocarpamine was partially synthesized from geissoschizine methylether, using C/D ring opening and reclosing reactions with cyanogen bromide and HOAc-NH4OAc respectively; determination of the absolute configuration of pleiocarpamine was accomplished by this chemical correlation.